Luminescent molecular switches based on dicationic P-doped polycyclic aromatic hydrocarbons

Extended O‐Doped Polycyclic Aromatic Hydrocarbons

The synthesis of O-doped benzorylenes, in which peripheral carbon atoms have been replaced by oxygen atoms, has been achieved for the first time. This includes key high-yielding ring-closure steps which, through intramolecular C-O bond formation, allow stepwise planarization of oligonaphthalenes. Single-crystal X-ray diffraction showed that the tetraoxa derivative forms remarkable face-to-face ...

Capillary Electrochromatography: Polycyclic Aromatic Hydrocarbons

Electrochromatography is utilized to separate a mixture of 16 different polycyclic aromatic hydrocarbons (PAHs). Fused-silica capillary columns ranging in size from 50 to 150 pm i.d. were packed (20-40-cm sections) with 3-pm octadecylsilica particles. A potential of 15-30 kV is applied across the 30-50-cm total length capillary column to generate electroosmotic flow that carries the PAHs throug...

Polycyclic aromatic hydrocarbons in carcinogenesis.

A symposium on "Polycyclic Aromatic Hydrocarbons (PAHs) in Carcinogenesis" was presented at the third International Congress of Pathophysiology held in Lathi, Finland, 28 June-3 July 1998. The congress was also sponsored by the International Union of Biological Sciences and the International Society of Free Radical Research. Institutional support for the symposium included the Electric Power Re...

Polycyclic aromatic hydrocarbons (PAH) guidance

Biodegradation of high-molecular-weight polycyclic aromatic hydrocarbons by bacteria.

Interest in the biodegradation mechanisms and environmental fate of polycyclic aromatic hydrocarbons (PAHs) is prompted by their ubiquitous distribution and their potentially deleterious effects on human health. PAHs constitute a large and diverse class of organic compounds and are generally described as molecules which consist of three or more fused aromatic rings in various structural configu...